AKS Group

Current group members: The AKS research group currently has the following members: Ph.D. Students Dibya Yadav M.Sc.: D.D.U.…More…AKS Group

Research

Ligand Design: One of the most reliable ways to obtain new catalysts with novel reactivity is tuning the…More…Research

Dr. Amrendra K. Singh
Associate Professor
Department of Chemistry
Indian Institute of Technology Indore
Simrol, Indore 453552, M.P., India
Phone: +91 731 660 3185
Email: aks[AT]iiti.ac.in

Research Interests

  • Ligand design in metal catalysis.
  • Multidentate N-heterocyclic carbene (NHC) ligands.
  • Redox-active NHCs and pincer ligands.
  • Small molecule activation by transition metal complexes.
  • Transition metal complexes with metal-ligand multiple bonds (MLMB).

Selected Publications

  • Yadav, D.; Singh, R. K.; Misra, S.; Singh, A. K. Ancillary Ligand Effects and Microwave-Assisted Enhancement on the Catalytic Performance of Cationic Ruthenium(II)-CNC Pincer Complexes for Acceptorless Alcohol Dehydrogenation. Appl. Organomet. Chem. 202236, e6756.
  • Singh, R. K.; Khan, T. K.; Misra, S.; Singh, A. K. CAACs as Efficient Ancillary Ligands for the Synthesis of Robust Catalysts. J. Organomet. Chem. 2021, 956, 122133.
  • Yadav, D.; Singh, R. K.; Singh, S.; Shirage, P. M.; Singh, A. K. Cationic Ruthenium(II)-NHC Pincer Complexes with Hemilabile COD: Solid-state Structural Characterisation and Theoretical Study of an η2-(E,Z)-COD Ligand. J. Organomet. Chem. 2021, 953, 122061.
  • Yadav, D.; Misra, S.; Kumar, D.; Singh, S.; Singh, A. K. Cationic Ruthenium(II)-NHC Pincer Complexes: Synthesis, Characterisation and Catalytic Activity for Transfer Hydrogenation of Ketones. Appl. Organomet. Chem. 2021, 35, e6287. (Author Share Link)
  • Abdel-Magied, A. F.; Theibich, Y.; Singh, A. K.; Rahaman, A.; Doverbratt, I.; Raha, A. K.; Haukka, M.; Richmond, M. G.; Nordlander, E. Asymmetric hydrogenation of an α-unsaturated carboxylic acid catalyzed by intact chiral transition metal carbonyl clusters–diastereomeric control of enantioselectivity. Dalton Trans. 2020, 49, 4244-4256.