{"id":1210,"date":"2023-10-26T08:41:05","date_gmt":"2023-10-26T03:11:05","guid":{"rendered":"https:\/\/people.iiti.ac.in\/~aks\/?p=1210"},"modified":"2023-10-26T08:41:06","modified_gmt":"2023-10-26T03:11:06","slug":"new-paper-in-dalton-transactions-2","status":"publish","type":"post","link":"https:\/\/people.iiti.ac.in\/~aks\/new-paper-in-dalton-transactions-2\/","title":{"rendered":"New paper in Dalton Transactions"},"content":{"rendered":"\n<p>One of our most awaited papers is now online, published in Dalton Transactions.<\/p>\n\n\n\n<p><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/DT\/D3DT03149G\">Role of ancillary ligands in selectivity towards acceptorless dehydrogenation versus dehydrogenative coupling of alcohols and amines catalyzed by cationic ruthenium(ii)\u2013CNC pincer complexes &#8211; Dalton Transactions (RSC Publishing)<\/a><\/p>\n\n\n\n<p>In this paper, we have described the unexpected reversal in the catalytic activity of cationic Ru(II)\u2013CNC pincer complexes for dehydrogenative coupling compared to acceptorless dehydrogenation, which can be explained using the trans effect of the auxiliary ligands (CO &gt; COD &gt; DMSO \u2248 PPh3).<\/p>\n\n\n\n<p>Congratulations, Rahul, Dibya and all co-authors!<\/p>\n","protected":false},"excerpt":{"rendered":"<p>One of our most awaited papers is now online, published in Dalton Transactions. Role of ancillary ligands in&hellip;<a href=\"https:\/\/people.iiti.ac.in\/~aks\/new-paper-in-dalton-transactions-2\/\" class=\"more-link\"><span class=\"more-button\">More&#8230;<span class=\"screen-reader-text\">New paper in Dalton Transactions<\/span><\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":1200,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[22],"tags":[],"class_list":["post-1210","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publications"],"_links":{"self":[{"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/posts\/1210","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/comments?post=1210"}],"version-history":[{"count":0,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/posts\/1210\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/media\/1200"}],"wp:attachment":[{"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/media?parent=1210"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/categories?post=1210"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/people.iiti.ac.in\/~aks\/wp-json\/wp\/v2\/tags?post=1210"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}